Volume III/7
: Crystal Structure Data of Inorganic Compounds 
Editors: K.-H. Hellwege and A.M. Hellwege Authors: W. Pies, A. Weiss. In cooperation with H.-P. Boehm, H.J. Meyer (c3); G. Will (d1a); G. Pieper (d1); 
R.
 Allmann (d2)

Part b3
: Key Elements: S, Se, Te 
1982.

 9 figs., XXVII, 435 pages. ISBN 3-540-11622-2Contents Introduction	XIII

1 Subject matter	XIII

2 	Arrangement of the substances XIII

 Survey: Distribution of substances within subvolumes III/7a ... III/7hXIV

3 	Selection and arrangement of information in the tables XVII

 3.1 
Selection of information	XVII

 3.2 
Arrangement of information	XVIII



 3.3 Reference sources XXIII 4 References used in the introduction XXV 5 List of space-group symbols for various settings see volume III/7a, page XXIV 6 List of symbols and abbreviations XXVI 
Tables
IV Compounds with the key element sulfur 1

 IV.1 
Sulfides	1

 IV.1.1 
Simple and complex sulfides including polysulfides	1

 IV.1.1.1 
Simple and complex sulfides without H2O, NH3	1

 IV.1.1.2 
Simple and complex sulfides with H2O, NH3	20



 IV.1.2 
Anhydrous sulfides with additional anions	23

 IV.1.2.1 
Sulfides with F-as additional anion	23

 IV.1.2.2 
Sulfides with Cl-as additional anion	27

 IV.1.2.3 
Sulrides with Br-as additional anion	31

 IV.1.2.4 
Sulfides with I-as additional anion	38

 IV.1.2.5 
Sulfides with halogenometallate anions	47

 IV.1.2.6 
Sulfides with O2-as additional anion	48



 IV.1.2.7 
-Sulfides with OH-, ClO4 ... as additional anions	62

 IV.1.3 
Sulfides with additional anions and H2O, NH3	63



 IV.2 
Trioxosulfates(IV) (sulfites)	64

 IV.2.1 
Anhydrous sulfites	64

 IV.2.2 
Sulfites with H2O, NH3	66

 IV.2.3 
Sulfites with additional anions (without/with H2O, NH3)	71



 IV.3 
Tetraoxosulfates(VI) (sulfates)	72

 IV.3.1 
Anhydrous sulfates	72

 IV.3.2 
Sulfates with H2O, NH3	145

 IV.3.2.1 
Sulfates with H2O 	145

 IV.3.2.2 
Sulfates with NH3, N2H4, 	224



 IV.3.3 
Anhydrous sulfates with additional anions	225

 IV.3.3.1 
Sulfates with F-, Cl, Br, I as additional anions	225

 IV.3.3.2 
Sulfates with O2-as additional anion	229

 IV.3.3.3 
Sulfates with OH-as additional anion	239



 IV.3.3.4 
-Sulfates with OH and O2-as additional anions	248

 IV.3.3.5 
-Sulfates with further anions (BrO3, IO-3, ...)249

 IV.3.4 
Sulfates with additional anions and H2O, NH3, ...250



-IV 3.4.1 Sulfates with F-, Cl, ... and H2O 	250

 IV.3.4.2 
Sulfates with O2-as additional anion and H2O 	251

 IV.3.4.3 
Sulfates with OH-as additional anion and H2O 	256

 IV.3.4.4 
Sulfates with OH-and F, Cl,... as additional anions, and H2O 	272

 IV.3.4.5 
Sulfates with F, Cl, ... O2-, ... as additional anions and H2O, NH3	276



 IV.4 
Further oxo-compounds of sulfur 279

 IV.4.1 
Sulfoxylates R2SO2 279

 IV.4.2 
Dithionites Men(S2O4)2-280
 IV.4.3 
Dithionates Men(S2O6)2-280
 IV.4.3.1 
Anhydrous dithionates 280

 IV.4.3.2 
Dithionates with H2O, NH3 282

 IV.4.3.3 
Further dithionates 284



 IV.4.4 
Polythionates Men(SxO6)2-(x 7 3) 285

 IV.4.4.1 
Anhydrous polythionates 285

 IV.4.4.2 
Polythionates with H2O 287



 IV.4.5 
Disulfites Men(S2O5)2-289
 IV.4.6 
Disulfates Men(S2O7)2-and polysulfates Men(S1+nO4+3n)2-290
 IV.4.7 
Peroxomonosulfates Men(SO5)2-292
 IV.4.8 
Peroxodisulfates Men(S2O8)2-292
 IV.4.9 
Halogenosulfates Men(SO3X)-293
 IV.4.9.1 
Fluorosulfates 293

 IV.4.9.2 
Chlorosulfates 295



 IV.4.10 
Thiosulfates Men(S2O3)2-295
 IV.4.10.1 
Anhydrous thiosulfates 295

 IV.4.10.2 
Simple thiosulfates with H2O 296

 IV.4.10.3 
Complex thiosulfates with H2O, NH3, ...299

 IV.4.10.4 
Thiosulfates with additional anions (without/with H2O) 300



 IV.4.11 
Oxo-compounds of sulfur with S-N-bondings 302

 IV.4.11.1 
Nitridosulfates (NSOx)n-302
 IV.4.11.2 
Imidosulfates (HN(SO3)2)2-302
 IV.4.11.3 
Amidosulfates (H2NSO3)-303
 IV.4.11.4 
Hydroxylamidosulfates (H2NOSO3)-305
 IV.4.11.5 
Nitrososulfites 306







V Compounds with the key elements selenium and tellurium 308

 V.1 
Selenides and oxo-compounds of selenium 308

 V.1.1 
Selenides) 308

 V.1.1.1 
Simple and complex selenides (without H2O, NH3) 308

 V.1.1.2 
Selenides with H2O, NH3 312

 V.1.1.3 
Selenides with additional anions 313

 V.1.1.3.1 
Selenides with F-as additional anion 313

 V.1.1.3.2 
Selenides with Cl-, Br-or I-as additional anion 317

 V.1.1.3.3 
Selenides with O2-as addition al anion (oxide selenides) 322

 V.1.1.3.4 
Selenides with S2-as additional anion 326





 V.1.2 
Trioxoselenates(IV) (Selenites) 327

 V.1.2.1 
Anhydrous selenites 327

 V.1.2.2 
Selenites with H2O 335

 V.1.2.3 
Selenites with additional anions (without/with H2O) 338



 V.1.3 
Tetraoxoselenates(VI) (Selenates) 340

 V.1.3.1 
Anhydrous selenates 340

 V.1.3.2 
Selenates with H2O 350

 V.1.3.3 
Selenates with NH3 361

 V.1.3.4 
Anhydrous selenates with additional anions 362

 V.1.3.5 
Selenates with additional anions and H2O, NH3 364



 V.1.4 
Further oxo-compounds of selenium 365

 V.1.4.1 
Diselenites Men(Se2O5)-365
 V.1.4.2 
Selenotrithionates Men(Se(SO3)2)2-and selenopentathionates Men(Se(S2O3)2)2-367
 V.1.4.3 
Halogenooxoselenates 369

 V.1.4.4 
Nitridoselenates 369



 V.1.5 
Halogenoselenates with SO-group as ligand 370



 V.2 
Tellurides and oxo-compounds of tellurium 370

 V.2.1 
Tellurides 370

 V.2.1.1 
Simple tellurides (without/with H2O) 370

 V.2.1.2 
Tellurides with additional anions 370

 V.2.1.2.1 
Tellurides with F-as additional anion	370

 V.2.1.2.2 
Tellurides with Cl-as additional anion	371

 V.2.1.2.3 
Tellurides with Br-as additional anion	372

 V.2.1.2.4 
Tellurides with I-as additional anion	374

 V.2.1.2.5 
Tellurides with O2-as additional anion	376

 V.2.1.2.6 
Tellurides with further anions	379





 V.2.2 
Oxo-compounds of tellurium	380

 V.2.2.1 
Oxo-compounds of Te(IV)	380

 V.2.2.1.1 	
Anhydrous oxo-compounds of Te(IV) 380

 V.2.2.1.2 	
Oxo-compounds of Te(IV) with H2O, NH3 398

 V.2.2.1.3 	
Oxo-compounds of Te(IV) with F-, Cl-, ... O2-, ... as additional anions (without/with



 H2O) 400

 V.2.2.2 
Oxo-compounds with Te(IV, VI)	403

 V.2.2.3 
Oxo-compounds of Te(VI)	404

 V.2.2.3.1 
Anhydrous oxo-compounds of Te(VI)	404

 V.2.2.3.2 
Oxo-compounds of Te(VI) with H2O 	430

 V.2.2.3.3 
Hydroxo- and oxohydroxo-compounds of Te(VI)	430



 V.2.2.4 
Further oxo-compounds of tellurium	432

 V.2.2.4.1 
Telluropentathionates Men(Te(S2O3)2)2-	432
 V.2.2.4.2 
Halogenooxotellurates	433



 V.2.2.5 
Halogenotellurates with SO-group as ligand	435

 V.2.2.6 
Thiotellurates	435











 References for III/7 subvolume III/7g Over-all list of contents of volume III/7 subvolume III/7h Alphabetical formula index subvolume III/7h Alphabetical mineral name index subvolume III/7h 
