Landolt-Brnstein Group II
: Molecules and Radicals
Volume 13 

Radical Reaction Rates in Liquids 

Subvolume E Proton and Electron Transfer. Biradicals 
Introductory material 
General introduction (H. FISCHER) 1

9 
Proton transfer reactions and equilibria of radicals (J.K. DOHRMANN) 5

9.0 
Introduction 5

9.1 
Carbon-centered radicals 10

9.2 
Oxyl and peroxyl radicals 67

9.3 
Aroxyl and semiquinone radicals 69

9.4 
Nitroxyl radicals 84

9.5 
Nitrogen-centered radicals 87

9.6 
Radicals from nitroso and nitro compounds 92

9.7 
Sulfur-centered radicals 103

9.8 
Radicals from heterocyclic compounds 106

10 
Electron transfer equilibria involving radicals and radical ions in aqueous solutions 147

(S.
 STEENKEN)
10.0 
Introduction 147

10.1 
Rate and equilibrium constants for electron exchange reactions 150

10.2 
E1x (O/S), potentials for the one-electron reduction of O 178

10.3 
E2x (S/R), Potentials for the one-electron reduction of S 259

11 
Biradicals (J.C. SCAIANO) 294

11.0 
General introduction 294

11.1 
Unimolecular biradical processes 297

11.2 
Biradical self-reactions 317

11.3 
Biradical-molecule reactions (absolute rate measurements) 317

11.4 
Competitive kinetic measurements 333

11.5 
Biradical quenching of excited states 348

11.6 
Reactions of excited biradicals 360


Index of substances 364


