Landolt-Brnstein Group III
: Condensed Matter
Volume 19 

Magnetic Properties of Metals 
Subvolume A 3d, 4d and 5d Elements, Alloys and Compounds 
1
Magnetic properties of 3d, 4d and 5d elements, alloys and compounds 1 
1.1

3d elements 1 
1.1.1

Ti, V, Cr, Mn (J.J.M. FRANSE, R. GERSDORF) 1 
1.1.1.1

Ti 1 
1.1.1.2 
V6 
1.1.1.3

Cr 6 
1.1.1.4

Mn 17 
1.1.1.5

References for 1.1.1 22 
1.1.2

Fe, Co, Ni (M.B. STEARNS) 24 
1.1.2.1

Introduction 24 
1.1.2.2

Phase diagrams, lattice constants and elastic moduli 24 
1.1.2.3

Paramagnetic properties 30 
1.1.2.4

Spontaneous magnetization, magnetic moments and high-field susceptibility 34 
1.1.2.5

Magnetocrystalline anisotropy constants 41 
1.1.2.6

Magnetostriction coefficients 48 
1.1.2.7

Form factors, densities and magnetic moments 52 
1.1.2.8

Hyperfine fields, isomer shifts and relaxation time 58 
1.1.2.9

Spin wave properties 72 
1.1.2.10

g factors and ferromagnetic resonance properties 85 
1.1.2.11

Fermi surfaces, band structures, exchange energies and electron spin polarizations 91 
1.1.2.12

Optical constants, magneto-optic Kerr or Faraday effect 113 
1.1.2.13

Specific heat, resistivity, magnetoresistance, Hall coefficients, Seebeck coefficients 118 
1.1.2.14

References for 1.1.2 134 
1.2

Alloys between 3d elements 142 
1.2.1

Alloys between Fe, Co or Ni (D. BONNENBERG, K.A. HEMPEL, H.P.J. WIJN) 142 
1.2.1.1

Phase diagrams, lattice parameters 144 
1.2.1.2

Magnetic properties 152 
1.2.1.2.1

Paramagnetic properties 152 
1.2.1.2.2

Hyperfine magnetic fields, isomer shifts 157 
1.2.1.2.3

Spin waves 168 
1.2.1.2.4

Atomic magnetic moment, magnetic moment density, g and g' factor 174 
1.2.1.2.5

Spontaneous magnetization, Curie temperature 189 
1.2.1.2.6

High-field susceptibility 207 
1.2.1.2.7

Magnetocrystalline anisotropy 210 
1.2.1.2.8

Magnetostriction 222 
1.2.1.2.9

Magnetomechanical properties, elastic moduli, sound velocity 233 
1.2.1.2.10

Thermomagnetic properties, thermal expansion coefficient, specific heat, Debye 245 



Introductory material 
and thermal conductivity 
temperature, thermal conductivity 
1.2.1.2.11 
Galvanomagnetic properties 257

1.2.1.2.12 
Magneto-optical properties 267

1.2.1.2.13 
Ferromagnetic resonance properties 273

1.2.1.3 
References for 1.2.1 274

1.2.2 
Alloys between Ti, V, Cr or Mn (K. ADACHI) 282

1.2.2.0 
General remarks 282

1.2.2.1 
V-Ti 284

1.2.2.2 
Cr-Ti 287

1.2.2.3 
Cr-V 289

1.2.2.4 
Mn-Ti 295

1.2.2.5 
Mn-V 295

1.2.2.6 
Mn-Cr 300

1.2.3 
Alloys of Fe, Co or Ni and Ti, V, Cr or Mn (K. ADACHI) 311

1.2.3.0 
General remarks 311

1.2.3.1 
Fe-Ti 316

1.2.3.2 
Fe-V 323

1.2.3.3 
Fe-Cr 338

1.2.3.4 
Fe-Mn 362

1.2.3.5 
Co-Tl 374

1.2.3.6 
Co-V 380

1.2.3.7 
Co-Cr 384

1.2.3.8 
Co-Mn 391

1.2.3.9 
Ni-Ti 401

1.2.3.10 
Ni-V 405

1.2.3.11 
Ni-Cr 408

1.2.3.12 
Ni-Mn 414

1.2.3.13 
V-Cr-Mn 431

1.2.3.14 
Fe-V-Cr 435

1.2.3.15 
Fe-Cr-Mn 436

1.2.3.16 
Co-V-Cr 437

1.2.3.17 
Co-Cr-Mn 438

1.2.3.18 
Fe-Co-Ti 439

1.2.3.19 
Fe-Co-V 446

1.2.3.20 
Fe-Co-Cr 447

1.2.3.21 
Fe-Co-Mn 451

1.2.3.22 
Fe-Ni-V 458

1.2.3.23 
Fe-Ni-Cr 459

1.2.3.24 
Fe-Ni-Mn 464

1.2.3.25 
Co-Ni-Ti 477

1.2.3.26 
Co-Ni-Mn 477

1.2.3.27 
References for 1.2.2 and 1.2.3 480

1.3 
4d and 5d elements, alloys and compounds (S. MISAWA, K. KANEMATSU) 491

1.3.1 
Introduction to the paramagnetism of 4d and 5d transition metals 491

1.3.2 
Magnetic susceptibility 493

1.3.3 
Magnetic susceptibility as a function of composition 504

1.3.4 
High-field magnetization 506

1.3.5 
Magnetization density 508

1.3.6 
Knight shift 508

1.3.7 
Magnetostriction 512

1.3.8 
Magnetoresistance and Hall effect 513

1.3.9 
Magnetic field dependence of the electronic specific heat coefficient 515

1.3.10 
Effect of plastic deformation on the susceptibility 516

1.3.11 
References for 1.3 517

1.4 
Alloys and compounds of 3d elements and 4d or 5d elements 519

1.4.1 
3d elements and Zr, Nb, Mo or Hf, Ta, W, Re (M. SHIGA) 519

1.4.1.1 
Introduction 519

1.4.1.2 
Ti and V alloys and compounds 521

1.4.1.3 
Cr alloys and compounds 526

1.4.1.4 
Mn alloys and compounds 530

1.4.1.5 
Fe alloys and compounds 531

1.4.1.6 
Co and Ni alloys and compounds 551

1.4.1.7 
References for 1.4.1 564

1.4.2 
3d elements and Ru, Rh, Pd or Os, Ir, Pt (J.J.M. FRANSE, R. GERSDORF) 566

1.4.2.1 
3d-rich alloys 566

1.4.2.2 
Concentrated alloys and intermetallic compounds 577

1.4.2.2.0 
Introduction 577

1.4.2.2.1 
Sc, Ti, and V alloys and compounds 578

1.4.2.2.2 
Cr alloys and compounds 582

1.4.2.2.3 
Mn alloys and compounds 588

1.4.2.2.4 
Fe alloys and compounds 596

1.4.2.2.5 
Co alloys and compounds 613

1.4.2.2.6 
Ni alloys and compounds 618

1.4.2.3 
4d- and 5d-rich alloys 630

1.4.2.4 
References for 1.4.2 648


