Landolt-Brnstein Group III: Condensed Matter 
Volume 19 Magnetic Properties of Metals 
Subvolume C Alloys and Compounds of d-Elements with Main Group Elements. Part 2 
Introductory material 1 Magnetic properties of 3d, 4d and 5d elements, alloys and compounds 1 
1.1 - 1.4 See Vol. 19A 
1.5 Alloys and compounds of 3d elements with main group elements 1 
1.5.1 - 1.5.3 See Vol. 19B 
1.5.4 3d elements and C, Si, Ge, Sn or Pb (Y. NAKAMURA) 1 
1.5.4.1 Introduction 1 
1.5.4.2 Ti and V alloys and compounds 3 
1.5.4.3 Cr alloys and compounds 7 
1.5.4.4 Mn alloys and compounds 13 
1.5.4.5 Fe alloys and compounds 24 
1.5.4.5.1 Alloys and compounds with C and Si 24 
1.5.4.5.2 Alloys and compounds with Ge 45 
1.5.4.5.3 Alloys and compounds with Sn 55 
1.5.4.6 Co and Ni alloys and compounds 61 
1.5.4.7 MM'X ternary compounds 65 
1.5.4.8 References for 1.5.4 71 
1.5.5 Heusler alloys (P.J. WEBSTER, K.R.A. ZIEBECK) 75 
1.5.5.1 Crystallographic structure 75 
1.5.5.1.1 Chemical order 79 
1.5.5.1.1.1 General model 79 
1.5.5.1.1.2 A statistical model 82 
1.5.5.1.1.3 Preferential disorder 82 
1.5.5.1.2 Magnetic order 85 
1.5.5.1.2.1 Ferromagnetic order 85 
1.5.5.1.2.2 Antiferromagnetic order 86 
1.5.5.2 Bulk magnetic properties 87 
1.5.5.2.1 Introduction 87 
1.5.5.2.2 Ferromagnets X2MnZ 87 
1.5.5.2.2.1 X2MnZ with X = 3d element 87 
1.5.5.2.2.2 X2MnZ with X = 4d element 96 
1.5.5.2.3 Antiferromagnets X2MnZ 97 
1.5.5.2.3.1 X2MnZ with X = 3d element 97 
1.5.5.2.3.2 X2MnZ with X = 4d element 98 
1.5.5.2.3.3 X2MnZ with X = 5d element 99 
1.5.5.2.4 Ferromagnets X2YZ for Y other than Mn 100 
1.5.5.2.4.1 Co2YZ with Y = 4A, 5A element 100 
1.5.5.2.4.2 Co2YZ with Y = 6A, 7A element 103 
1.5.5.2.4.3 Fe2YZ with X = 6A, 8A element 104 
1.5.5.2.4.4 Fe2FeZ 104 
1.5.5.2.4.5 Mn2VZ 109 
1.5.5.2.5 
Paramagnets X2YZ with X, Y = 3d element 110

1.5.5.2.6 
Quaternary alloys 111

1.5.5.2.6.1 
(XX*)2MnSn with X, X* = 3d elements 111

1.5.5.2.6.2 
Ni2(YY*)Sn with Y, Y* = 3d elements 112

1.5.5.2.6.3 
(XX*)2TiSn with X, X* = 3d elements 113

1.5.5.2.6.4 
(XX*)2MnSn with X = 3d, X* = 4d element 114

1.5.5.2.6.5 
(XX*)2MnAl with X = 3d, X* = 4d element 115

1.5.5.2.6.6 
Pd2Mn (ZZ*) 116

1.5.5.2.7 
Clb Intermetallic compounds XYZ 117

1.5.5.2.7.1 
Ferromagnets XMnZ with X = 3d element 118

1.5.5.2.7.2 
Ferromagnets XMnZ with X = 4d, 5d element 119

1.5.5.2.7.3 
Ferromagnets - paramagnets XYSb for Y other than Mn 120

1.5.5.2.7.4 
Antiferromagnets XMnZ with X = 3d, 4d, 5d element 121

1.5.5.2.7.5 
Quaternary alloys (XX*)MnSb with X, X* = 3d, 4d, 5d elements 121

1.5.5.2.7.6 
X2-xMnSb with X = 3d, 4d element 123

1.5.5.3 
Neutron diffraction and magnetic order 124

1.5.5.3.1 
Introduction 124

1.5.5.3.2 
Neutron diffraction theory 124

1.5.5.3.3 
Magnetic and chemical ordering data 125

1.5.5.3.3.1 
Co2MnZ 125

1.5.5.3.3.2 
Ni2MnZ 127

1.5.5.3.3.3 
Pd2MnZ 129

1.5.5.3.3.4 
Au2MnZ 132

1.5.5.3.3.5 
Clb compounds XYZ 134

1.5.5.3.4 
Polarized neutron measurements on single crystals 139

1.5.5.3.4.1 
X2MnZ for X other than Co 139

1.5.5.3.4.2 
Fe3Z 143

1.5.5.3.4.3 
Fe3-xMnxSi 145

1.5.5.3.4.4 
Co2YZ with Y = 3d element 147

1.5.5.4 
Dynamics 149

1.5.5.4.1 
Lattice dynamics 150

1.5.5.4.2 
Phase transitions 151

1.5.5.4.3 
Spin dynamics 152

1.5.5.5 
Electrical properties 160

1.5.5.5.1 
Electrical resistivity 160

1.5.5.5.2 
Magnetoresistance 163

1.5.5.5.3 
Hall effect 165

1.5.5.5.4 
Thermoelectric power 167

1.5.5.6 
Thermal properties 168

1.5.5.6.1 
Specific heat 168

1.5.5.6.1.1 
Cu2MnZ 168

1.5.5.6.1.2 
Fe3-xMnxSi 169

1.5.5.6.1.3 
CoTi1-xAlx 170

1.5.5.6.2 
Superconductivity 171

1.5.5.7 
Hyperfine fields 172

1.5.5.7.1 
Introduction 172

1.5.5.7.2 
Mssbauer spectra of Sn-doped alloys (119Sn) 173

1.5.5.7.2.1 
X2MnIn with X = 1B, 8A element 173

1.5.5.7.2.2 
X2MnSb, XMnSb with X = 8A element 174

Mssbauer spectra of Sb-based alloys (121Sb), X2MnSb, XMnSb with X = 1B, 8A 174

element
Mssbauer spectra of Sn-based alloys (119Sn), Co2YSn with Y = 4A element 175

D03, compounds Fe3Z 176

D03-L21 compounds Fe3-xYxSi with Y = 5A, 7A, 8A element 178

B2-L21 compounds Mn0.5V0.5-xAlx 181

References for 1.5.5 182

Metallic perovskites 186

(PH.
 L'HRITIER, D. FRUCHART, R. MADAR, R. FRUCHART)Introduction 186

Crystallographic properties of McXMf3 compounds 186

Magnetic and related data of McXMf3 compounds 195

McXTi3 197

McXCr3 197

McXM3 198

McXFe3 245

McXCo3 248

McXNi3 248

References for 1.5.6 249

Alloys and compounds of 4d or 5d elements with main group elements 254

(S.
 MISAWA, K. KANEMATSU)General remarks
Alloys and compounds of Zr
ZrHx
ZrCuAl
ZrZn2
Other compounds of Zr
Alloys and compounds of Nb
Nb4 hydride
A15 and sigma-phase alloys of Nb
Nb carbides
Nb nitride
Nb chalcogenides
Alloys and compounds of Mo
Mo borides
MoAlGe
Mo carbides
Mo chalcogenides
Compounds of Ru
Alloys of Rh
Alloys and compounds of Pd
Pd hydrides
Pd-Li and Pd-Na compounds
fcc alloys of Pd
Other compounds of Pd
Alloys and compounds of Hf
Hf hydrides
HfZn2
Hf carbides

254 
257 
257 
257 
258 
265 
266 
266 
269 
271 
272 
273 
276 
276 
277 
277 
277 
281 
284 
285 
285 
288 
289 
292 
293 
293 
293 
294 




1.6.8.4 
Hf chalcogenides 294

1.6.9 
Alloys and compounds of Ta 295

1.6.9.1 
Ta hydrides 295

1.6.9.2 
Ta carbides 296

1.6.9.3 
Ta chalcogenides 297

1.6.10 
Alloys and compounds of W 298

1.6.10.1 
W borides 298

1.6.10.2 
WP 298

1.6.10.3 
W chalcogenides 298

1.6.11 
Alloys and compounds of Re 298

1.6.12 
Compounds of Os 299

1.6.13 
Alloys and compounds of Pt 300

1.6.13.1 
Pt-Li and Pt-Na compounds 300

1.6.13.2 
fcc alloys of Pt 300

1.6.13.3 
Other compounds of Pt 302

1.6.14 
References for 1.6 304


1.5.5.7.3 
1.5.5.7.4 
1.5.5.7.5 
1.5.5.7.6 
1.5.5.7.7 
1.5.5.8 
1.5.6 
1.5.6.1 
1.5.6.2 
1.5.6.3 
1.5.6.3.1 
1.5.6.3.2 
1.5.6.3.3 
1.5.6.3.4 
1.5.6.3.5 
1.5.6.3.6 
1.5.6.4 
1.6 
1.6.1 
1.6.2 
1.6.2.1 
1.6.2.2 
1.6.2.3 
1.6.2.4 
1.6.3 
1.6.3.1 
1.6.3.2 
1.6.3.3 
1.6.3.4 
1.6.3.5 
1.6.4 
1.6.4.1 
1.6.4.2 
1.6.4.3 
1.6.4.4 
1.6.5 
1.6.6 
1.6.7 
1.6.7.1 
1.6.7.2 
1.6.7.3 
1.6.7.4 
1.6.8 
1.6.8.1 
1.6.8.2 
1.6.8.3 

