Landolt-Brnstein Group III

: Condensed MatterVolume 27 Magnetic Properties of Non-Metallic Inorganic Compounds Based on Transition Elements Subvolume A
Pnictides and Chalcogenides I
1
Magnetic properties of pnictides and chalcogenides 1 
1.1

Pnictides and chalcogenides based on 3d transition elements 1 
1.1.1

Introduction 1 
1.1.1.1

General remarks 1 
1.1.1.2

List of frequently used symbols and abbreviations 1 
1.1.2

Compounds with pyrite, marcasite and arsenopyrite structures 7 
1.1.2.1

MX2 compounds with pyrite (FeS2) type structure 8 
1.1.2.1.1

MnX2 (X = S, Se, Te) 15 
1.1.2.1.2

FeX2 (X = S, Se, Te) 18 
1.1.2.1.3

CoX2 (X = S, Se, Te) 20 
1.1.2.1.4

NiX2 (X = S, Se, Te) 28 
1.1.2.1.5

CuX2 (X = S, Se, Te) 33 
1.1.2.1.6

ZnX2 (X = S, Se) 36 
1.1.2.2

MxM'1-xX2 mixed systems with pyrite (C2) type structure 37 
1.1.2.2.1

CrxCo1-xS2 37 
1.1.2.2.2

MnxM'1-xX2 (M' = Fe, Mg, Cu, Zn; X = S, Se, Te) 37 
1.1.2.2.3

1-xM'xS2 (M' = Co, Ni) 41 
1.1.2.2.4

1-xNixS2 45 
1.1.2.2.5

1-xCuxS2 46 
1.1.2.3

2-xSex mixed systems with pyrite (C2) type structure 47 
1.1.2.3.1

CoS2-xSex 47 
1.1.2.3.2

NiS2-xSex 52 
1.1.2.4

MYxX2-x and M1-xM'xYX mixed systems with cobaltite or pyrite (C2) type structure 54 
1.1.2.4.1

CoPxS2-x 55 
1.1.2.4.2

CoAsxS2-x 56 
1.1.2.4.3

NiPS 57 
1.1.2.4.4

NiAsxS2-x 58 
1.1.2.4.5

1-xNixAsS 58 
1.1.2.5

MX2, MY2, MxM'l-xY2 and MY2-xXx compounds with marcasite (C18) type structure 59 
1.1.2.5.1

CrSb2 60 
1.1.2.5.2

FeP2 61 
1.1.2.5.3

FeAs2 61 
1.1.2.5.4

FeSb2 61 
1.1.2.5.5

CoSb2 62 
1.1.2.5.6

CoTe2 63 
1.1.2.5.7

NiAs2 (beta-NiAs2) 63 
1.1.2.5.8

NiSb2 63 
1.1.2.5.9

1-xM'xY2 (M, M' = Cr, Fe, Ni; Y = As, Sb) 64 
1.1.2.5.10

FeAs2-xSex 64 






(K.
 ADACHI, S. OGAWA)
1.1.2.6 
MYxX2-x and MY2 compounds with arsenopyrite (E07) type structure	64

1.1.2.6.1 
FeSbxTe2-x	64

1.1.2.6.2 
CoP2	64

1.1.2.6.3 
CoAs2	65

1.1.2.6.4 
CoSb2	65

1.1.2.7 
References for 1.1.2	65

1.1.3 
Compounds with NiAs and MnP structures	70

1.1.3.1 
Ml-xX chalcogenides with NiAs type structure and their mixed systems	70

1.1.3.1.1 
Ti1-xX (X = S, Se, Te)	81

1.1.3.1.2 
V1-xX (X = S, Se, Te)	81

1.1.3.1.3 
Cr1-xX (X = S, Se, Te)	83

1.1.3.1.4 
MnX (X = S, Se, Te)	88

1.1.3.1.5 
Fe1-xX (X = S, Se, Te)	89

1.1.3.1.6 
Co1-xX (X = S. Se, Te)	92

1.1.3.1.7 
Ni1-xX (X = S, Se, Te)	93

1.1.3.1.8 
References for 1.1.3.1	140

1.1.3.2 
MY pnictides with MnP and NiAs type structures and their mixed systems	148

1.1.3.2.1 
MP (M = V, Cr, Mn, Fe)	159

1.1.3.2.2 
MAs (M = Ti, V, Cr, Mn, Fe, Co, Ni)	163

1.1.3.2.3 
MSb (M = Ti, V, Cr, Mn, Fe, Co, Ni)	170

1.1.3.2.4 
MBi (M = Mn, Ni)	180

1.1.3.2.5 
Mn1-xMxP (M = V, Cr, Fe, Co)	182

1.1.3.2.6 
MnP1-xAsx	190

1.1.3.2.7 
Mn1-xMxAs (M = Ti, V, Cr, Fe, Co, Ni)	197

1.1.3.2.8 
MnAs1-xSbx	206

1.1.3.2.9 
Mn1-xMxSb (M = Ti, V, Cr, Fe, Co, Ni)	208

1.1.3.2.10 
MnSb1-xSnx	213

1.1.3.2.11 
Arsenides containing Cr	214

1.1.3.2.12 
Antimonides containing Cr	221

1.1.3.2.13 
Other mixed pnictides containing Fe	224

1.1.3.2.14 
References for 1.1.3.2	227

1.1.4 
Compounds and mixed systems with Fe2P and Cu2Sb structures	232

1.1.4.1 
M2P compounds with Fe2P type structure and their mixed systems	232

1.1.4.1.1 
M2P (M = Mn, Fe, Co, Ni)	236

1.1.4.1.2 
Mixed system (M, M')2P (M, M' = Co, Mn, Fe, Ni)	248

1.1.4.1.3 
Fe2AsxPl-x and related systems containing As	261

1.1.4.1.4 
Other mixed systems containing P	263

1.1.4.1.5 
References for 1.1.4.1	264

1.1.4.2 
M2Y compounds with Cu2Sb type structure and their mixed systems	265

1.1.4.2.1 
M2As (M = Cr, Mn, Fe)	269

1.1.4.2.2 
M2Sb (M = Mn, Cu)	270

1.1.4.2.3 
MnMGe (M = Al, Ga)	273

1.1.4.2.4 
(M, M')2Y and M2(Y, Y') compounds (M, M' = 3d metals; Y, Y' = Sb, As)	275

1.1.4.2.5	
Mn1-xMx(Al, Ga)Ge (M = 3d metals) 284

1.1.4.2.6	
References for 1.1.4.2 286

1.1.5	
Chalcogenide spinels and their mixed systems 288

References for 1.1.5 373

1.1.6	
Other pnictides and chalcogenide 383

1.1.6.1	
Chalcopyrite, CuFeS2, and its Fe-substituted systems 383

1.1.6.2 
Anti-CaF2 type antimonides, M'MSb, and their mixed systems 385

1.1.6.3 
Heusler type antimonides, M'2MSb, and their mixed systems 400

1.1.6.4 
References for 1.1.6 423




Introductory material 
