Landolt-Brnstein Group II
: Molecules and Radicals
Volume 17 
Magnetic Properties of Free Radicals Subvolume D1
Nitroxide Radicals. Part 1

Title Page, Preface 
General introduction (H. FISCHER) 1


6 
Nitroxide radicals (A.R. FORRESTER) 5

6.1 
Introduction 5

6.2 
Nitroxides formed by trapping with nitrosoalkanes 8

6.2.1 
Methyl-nitrosopropane (MNP) 8

6.2.1.1 
Radicals derived from amino acids and peptides 8

6.2.1.2 
Radicals derived from nucleosides and nucleic acid bases 76

6.2.1.3 
Radicals derived from carbohydrates and their derivatives 104

6.2.1.4 
Hydrogen atorns 110

6.2.1.5 
Primary alkyl radicals 111

6.2.1.6 
Secondary alkyl radicals 132

6.2.1.7 
Tertiary alkyl radicals 154

6.2.1.8 
Polyhaloalkyl radicals 162

6.2.1.9 
Substituted vinyl radicals 165

6.2.1.10 
Aryl radicals 168

6.2.1.11 
Imidoyl radicals 175

6.2.1.12 
Cyano radicals 177

6.2.1.13 
Acyl radicals 177

6.2.1.14 
Aminyl radicals 182

6.2.1.15 
Oxyl radicals 184

6.2.1.16 
Thiyl radicals 190

6.2.1.17 
Sulfonyl and related radicals 194

6.2.1.18 
Boron-centred radicals 198

6.2.1.19 
Phosphorus-centred radicals 200

6.2.1.20 
Arsenic-centred radicals 201

6.2.1.21 
Silyl radicals 201

6.2.1.22 
Chromium-centred radicals 202

6.2.1.23 
Manganese-centred radicals 202

6.2.1.24 
Iron-centred radicals 202

6.2.1.25 
Other metal-centred radicals 203

6.2.2 
Methyl-nitrosobutanone 203

6.2.3 
Nitrosotryptycene 204

6.2.4 
Trifluoronitrosomethane 206

6.3	
Nitroxides formed by trapping with nitrosoarenes, nitrosoheterocycles and 212

nitroarenes

6.3.1	
Nitrosobenzene and nitrobenzene 212

6.3.2	
2,6-Dichloronitrosobenzene 233

6.3.3	
2,4,6-Trichloronitrosobenzene 238

6.3.4	
2,4,6-Tribromonitrosobenzene 251

6.3.5	
2,6-Dibromobenzene-sulfonate 255

6.3.6	
2,4,6-Trimethylnitrosobenzene and 2,4,6-trimethylnitrobenzene 262

6.3.7	
Nitrosodurene 268

6.3.8	
3,5-Di-t-butylnitrosobenzene 325

6.3.9	
2,4,6-Tri-t-butylnitrosobenzene and 2,4,6-tri-t-butylnitrobenzene 328

6.3.10	
Sodium 2,6-di(trideuteromethyl)-4,5-dideuteronitrosobenzene-3-sulfonate 347

6.3.11	
Pentafluoronitrosobenzene 351

6.3.12	
Pentamethoxynitrosobenzene 352

6.3.13	
Pentamethylnitrosobenzene 356

6.3.14	
3,5-Diphenyl-1-methyl-4-nitrosopyrazole 360

6.3.15	
Sodium (3',5'-diphenyl-4'-nitrosopyrazol-1'-yl)propane-1-sulfonate 364

6.3.16	
Nitrosopyridine 1-oxide 365

6.3.17	
Dimethyl-nitrosopyridine 1-oxide 366

6.3.18	
Other nitrosoarenes 368

6.3.19	
Other nitroarenes 377

References for 6.2 and 6.3 390

General symbols and abbreviations (H. FISCHER)	402






Index of Substances (See Vol. 17H) 
