Landolt-Brnstein Group II
: Molecules and Radicals
Volume 18 

Radical Reaction Rates in Liquids 

Subvolume C Nitrogen-Centered Radicals, Aminoxyls and Related Radicals 
Introductory material 
General introduction (H. FISCHER) 
5	
Nitrogen-centered radicals (K.U. INGOLD, J.C. WALTON) 1

5.0	
Introduction 1

5.1	
Aminyl radicals, RR'N 3

5.2	
Aminium radicals, RR'R"N 59

5.3	
Carboxamidyl radicals, RR'CON 120

5.4	
Sulfinamidyl radicals, RR'SON, and sulfonamidyl radicals, RR'SO2N 127

5.5	
Imidyl radicals, RCOR'CON 129

5.6	
Iminyl radicals, RR'C=N, and isocyanatyl radicals, O=C=N 142

5.7	
Alkoxyaminyl radicals, RR'ON and ROR'ON 144

5.8	
Thioaminyl radicals, RR'SN 146

5.9	
Dithioaminyl radicals, RSR'SN 155

5.10	
Hydrazyl radicals, R'R"NNR 158

5.11	
Hydrazyl radical cations, (R'R"NNR2)+ and related species 164

5.12	
Verdazyl and related radicals 167

5.13	
Diazirinyl radicals (no entries) 202

5.14	
Diazenyl radicals, RN=N 202

5.15	
Azidyl radical 214

5.16	
Triazenyl radicals and azallyl radicals 224

5.17	
Radical ions 224

5.18	
Dithiadiazolyl radicals and related cyclic polyaza radicals and radical cations 235

References for 5 240

6	
Aminoxyl and related radicals (K.U. INGOLD) 251

6.0	
Introduction 251

6.1	
Aminoxyl radicals, RR'NO 253

6.1.1	
Bimolecular self-reactions and radical-dimer equilibria 253

6.1.2	
Reactions with a different radical 276

6.1.3	
Unimolecular reactions 368

6.1.4	
Intermolecular hydrogen-atom abstractions from carbon 400

6.1.5	
Intermolecular hydrogen-atom abstractions from oxygen 422

6.1.6	
Intermolecular hydrogen-atom abstractions from nitrogen 477

6.1.7	
Intermolecular reactions with molecules in excited states 500

6.1.8	
Other intermolecular reactions 519

6.2	
Iminoxyl radicals, RR'C=NO 586

References for 6 588

Index of substances for Vols. 13 and 18



