Landolt-Brnstein Group III
: Condensed Matter
Volume 27 

Magnetic Properties of Non-Metallic Inorganic Compounds Based on Transition Elements 

Subvolume F3 Perovskites II, Oxides with Corundum, Ilmenite and Amorphous Structures 
Introductory material 
5	
Magnetic properties of oxides with perovskite, corundum, ilmenite and amorphous 1

structures

5.1.1
 - 5.1.9See Vol. 27F1a 
5.1.10
 - 5.3See Vol. 27F1b 
5.4 
See Vol. 27F2 
5.5

Perovskite-type oxides RMO3 (R = rare earth element, M = 3d element or Al) 1 
5.5.1

Introduction 1 
5.5.1.1

General remarks 1 
5.5.1.2

Magnetic configurations 2 
5.5.1.3

List of frequently used symbols and abbreviations 5 
5.5.2

RAlO3 compounds 8 
5.5.3

RScO3 compounds 22 
5.5.4

RTiO3 compounds 25 
5.5.5

RVO3 compounds 46 
5.5.6

RCrO3 compounds 56 
5.5.7

RMnO3 compounds. 91 
5.5.8

RFeO3 compounds 101 
5.5.8.1

LaFeO3 compounds 104 
5.5.8.2

CeFeO3 107 
5.5.8.3

PrFeO3 107 
5.5.8.4

NdFeO3 compounds 108 
5.5.8.5

SmFeO3 compounds 110 
5.5.8.6

EuFeO3 compounds 116 
5.5.8.7

GdFeO3 compounds 118 
5.5.8.8

TbFeO3 compounds 120 
5.5.8.9

DyFeO3 compounds 125 
5.5.8.10

HoFeO3 compounds 134 
5.5.8.11

ErFeO3 compounds 138 
5.5.8.12

TmFeO3 compounds 143 
5.5.8.13

YbFeO3 146 
5.5.8.14

LuFeO3 compounds 146 
5.5.8.15

YFeO3 compounds 147 
5.5.9

RCoO3 compounds 152 
5.5.10

RNiO3 compounds 158 
5.5.11

References for 5.5 159 
5.6

Oxides with corundum and ilmenite structures	173 
5.6.1

Introduction 173

5.6.2

List of frequently used symbols and abbreviations 173

(H.P.J.
 WIJN)
(Y.
 ENDOH, K. KAKURAI, A.K. KATORI)


5.6.3 
Oxides with corundum structure 176

5.6.3.1 
Binary oxides M2O3; M = 3d transition element 177

5.6.3.2 
Pseudo-binary and ternary oxides (M1-xM'x)2O3; M, M' = 3d transition elements 190

5.6.4 
Oxides with ilmenite structure 205

5.6.4.1 
Single ternary oxides M'O3; M, M' = 3d transition elements 205

5.6.4.2 
Mixed pseudo-ternary Ti oxides (MxM'1-x)TiO3; M, M' = Mn, Fe,Co or Ni 221

5.6.5 
Solid solutions between oxides with corundum and ilmenite structure 233

5.6.6 
References for 5.6 235

5.7 
Amorphous oxides (M.S. SEEHRA, G. SRINIVASAN) 239

5.7.1 
Introduction 239

5.7.1.0 
Scope of the review 239

5.7.1.1 
Symbols and abbreviations 240

5.7.2 
Oxide glasses 242

5.7.2.0 
General remarks 242

5.7.2.1 
Phosphate glasses 242

5.7.2.1.0 
General remarks 242

5.7.2.1.1 
Ti-based phosphates 243

5.7.2.1.2 
V-based phosphates 244

5.7.2.1.3 
Cr-based phosphates 244

5.7.2.1.4 
Mn-based phosphates 246

5.7.2.1.5 
Fe-based phosphates 246

5.7.2.1.6 
Co-based phosphates 247

5.7.2.1.7 
Spinel ferrite based phosphates 248

5.7.2.2 
Borate glasses 249

5.7.2.2.0 
General remarks 249

5.7.2.2.1 
Mn-borate glasses 250

5.7.2.2.2 
Fe-alkali-borate glasses 252

5.7.2.2.3 
Fe-BaO-borate glasses 253

5.7.2.2.4 
Fe-CaO-borate glasses 256

5.7.2.3 
Silicate glasses 259

5.7.2.3.0 
General remarks 259

5.7.2.3.1 
Mn-aluminosilicate glasses 259

5.7.2.3.2 
Mixed-valence Fe-silicate glasses 261

5.7.2.3.3 
Ferrous-silicate glasses 263

5.7.2.3.4 
Co-aluminosilicate glasses 264

5.7.3 
Amorphous oxides prepared by various techniques 267

5.7.3.1 
Amorphous 3d oxides 267

5.7.3.1.0 
General remarks 267

5.7.3.1.1 
Cr-oxides 267

5.7.3.1.2 
Fe (ferric)-oxides 267

5.7.3.2 
Mixed binary oxides 269

5.7.3.2.0 
General remarks 269

5.7.3.2.1 
Amorphous garnets 270

5.7.3.2.2 
Other mixed oxides 275

5.7.3.2.2.1 
ZnFe2O4 275

5.7.3.2.2.2 
Fe0.69Ga1.37O3 276

5.7.3.2.2.3 
(Fe2O3)x(SrO)1-x 278

5.7.3.2.2.4 
(Fe2O3)x(Bi2O3)1-x 279

5.7.3.2.2.5 
CoFe2O4 281

5.7.3.2.2.6 
CuFe2O4 282

5.7.3.2.2.7 
Bi2CuO4 284

5.7.3.3 
Fe2O3-Bi2O3-based ternary oxides 285

5.7.3.3.0 
General remarks 285

5.7.3.3.1 
Fe2O3 Li2O Bi2O3 oxides 286

5.7.3.3.2 
Fe2O3 K2O Bi2O3 oxides 289

5.7.3.3.3 
Fe2O3 CaO Bi2O3 oxides 290

5.7.3.3.4 
Fe2O3 ZnO Bi2O3 oxides 295

5.7.3.3.5 
Fe2O3 CuO Bi2O3 oxides 301

5.7.3.3.6 
Fe2O3 Bi2O3 ABO3 oxides 307

5.7.4 
Theoretical status 315

5.7.5 
References for 5.7 317


