LB-SEARCH 
LB-CONTENTS 
GROUP III
: Condensed Matter
VOLUME 42 

Physics of Covered Solid Surfaces 
SUBVOLUME A2 Adsorbed Layers on Surfaces. Part 2
: Measuring Techniques and Surface Properties Changed by
Adsorption 

Title Page, Preface, Contributors 
2	
Characterization of adsorbate overlayers: measuring techniques (CH. WLL) 1

2.1	
Introduction 1

2.2	
Direct methods 4

2.3	
Techniques based on a mass spectrometer 7

2.4	
Techniques for a chemical analysis 9

2.5	
Structural sensitive techniques 13

2.6	
Imaging techniques 21

2.7	
Vibrational spectroscopy of adsorbed particles 25

2.8	
Techniques probing the electronic structure 28

2.9	
Nonlinear optical techniques 32

2.10	
Bulk techniques - Nuclear Magnetic Resonance (NMR) and Electron Spin Resonance 33

(ESR)
References for 2 35

4	
Data: Adsorbate-induced changes of substrate properties 43

4.1	
Surface structure on metals and semiconductors 43

(M.A.
 VAN HOVE, K. HERMANN, P.R. WATSON)
4.1.1	
Introduction 43

4.1.2	
Relaxation vs. reconstruction 43

4.1.3	
Notations and conventions 45

4.1.4	
Organization of the tables 46

4.1.5	
Organization of data for individual structures 46

4.1.6	
Adsorption on fcc(111) 48

4.1.7	
Adsorption on hcp(0001) 48

4.1.8	
Adsorption on bcc(110) 49

4.1.9	
Adsorption on fcc (100) 49

4.1.10	
Adsorption on bcc (100), pure or alloyed 50

4.1.11	
Adsorption on fcc (110) 50

4.1.12	
Adsorption on hcp (10-10) 51

4.1.13	
Adsorption on bcc (211) 51

4.1.14	
Adsorption on bcc (111) 51

4.1.15	
Adsorption on Si, Ge and C(111) 51

4.1.16	
Adsorption on Si and Ge(100) 52

4.1.17	
Adsorption on diamond-like(311) 52

4.1.18	
Adsorption on zincblende(110) 52

4.1.18	
Adsorption on zincblende(110) 52

4.1.19	
Adsorption on zincblende(111) and (-1-1-1) 53

4.1.20	
Adsorption on zincblende(100) 53

4.1.21	
Adsorption on 6H-SiC(0001) 53

Acknowledgments 53

Tables for 4.1 54

Figures for 4.1 141

References for 4.1 151



4.2	
Electron work function of metals and semiconductors (K. JAKOBI) 165

4.2.1	
Introduction 165

4.2.2	
Rare gases 171

4.2.3	
Atomically chemisorbed adsorbates 177

4.2.4	
Small molecules 199

4.2.5	
Nonpolar hydrocarbons 215

4.2.6	
Polar hydrocarbons 222

4.2.7	
Halohydrocarbons 224

4.2.8	
Other hydrocarbons 226

4.2.9	
Alkali metals 227

4.2.10	
Noble metals 240

4.2.11	
3d transition metals 247

4.2.12	
4d transition metals 250

4.2.13	
5d transition metals 253

4.2.14	
Rare-earth metals 255

4.2.15	
Group IIa metals 257

4.2.16	
Group IIIa metals 259

4.2.17	
Group IVa elements 260

4.2.18	
Group Va elements 262

4.2.19	
Other elements 263

Figures for 4.2 264

References for 4.2 282



4.4	
Surface free energy and surface stress (D. SANDER, H. IBACH) 303

4.4.1	
Introduction 303

4.4.2	
Experimental determination of surface free energy 304

4.4.3	
Experimental determination of the absolute value of the surface stress 310

4.4.4	
Experimental determination of changes of surface stress due to adsorption 312

4.4.5	
Calculations of surface free energy and surface stress 315

4.4.6	
Data 320

4.4.7	
Clean surfaces 321

4.4.8	
Adsorbate-induced changes of surface free energy 336

4.4.9	
Adsorbate-induced changes of surface stress 338

4.5	
Surface phonon dispersion (M.A. ROCCA) 352

4.5.1	
Introduction 352

4.5.2	
Data collection 358

Acknowledgements 375

Figures for 4.5 376

References for 4.5 419





