Table of contents Magnetic Properties of Free Radicals Subvolume A: Inorganic Radicals, Metal Complexes and Nonconjugated Carbon Centered Radicals Part 1 
I Introduction 
I 
General introduction [H. Fischer] ............................. 1

A 
Definition and substances ................................. 1

B
 Magnetic properties .................................... 1

C 
Arrangements of the tables................................ 3

D 
Monographs, reviews and important conference proceedings .............. 4

II Data 
1 
Inorganic radicals and radical ions [R.F.C. Claridge] .................. 7

1.1 
Introduction ........................................ 7

1.1.1 
Extent and method of the survey............................. 7

1.1.2 
Radicals included in the survey ............................. 7

1.1.3 
Arrangements of the tables................................ 7

1.1.4 
Gas-phase free radicals.................................. 8

1.1.5 
Review articles...................................... 8

1.2 
Trapped electron ..................................... 9

1.3 
Hydrogen-centered radicals ................................ 9

1.4 
Lithium-centered radicals ................................. 12

1.5 
Boron-centered radicals .................................. 14

1.6 
Carbon-centered radicals ................................. 20

1.7 
Nitrogen-centered radicals ................................ 31

1.8 
Oxygen-centered radicals ................................. 34

1.9 
Fluorine-centered radicals ................................ 37

1.10 
Sodium-centered radicals ................................. 37

1.11 
Magnesium-centered radicals ............................... 38

1.12 
Aluminum-centered radicals ............................... 39

1.13 
Silicon-centered radicals ................................. 43

1.14 
Phosphorus-centered radicals ............................... 46

1.15 
Sulfur-centered radicals ................................. 49

1.16 
Chlorine-centered radicals ................................ 54

1.17 
Potassium-centered radicals ............................... 55

1.18 
Scandium-centered radicals ................................ 55

1.19 
Titanium-centered radicals................................ 56

1.20 
Vanadium-centered radicals ............................... 56

1.21 
Chromium-centered radicals ............................... 59

1.22 
Manganese-centered radicals............................... 60

1.23 
Cobalt-centered radicals ................................. 60

1.24 
Nickel-centered radicals ................................. 61

1.25 
Copper-centered radicals ................................. 61

1.26 
Zinc-centered radicals .................................. 63

1.27 
Gallium-centered radicals ................................. 63

1.28 
Germanium-centered radicals ............................... 65

1.29 
Arsenic-centered radicals ................................. 65

1.30 
Selenium-centered radicals................................ 66

1.31 
Bromine-centered radicals ................................ 67

1.32 
Yttrium-centered radicals ................................. 67

1.33 
Niobium-centered radicals ................................ 68

1.34 
Molybdenum-centered radicals .............................. 69

1.35 
Ruthenium-centered radicals............................... 70

1.36 
Palladium-centered radicals ................................ 70

1.37 
Silver-centered radicals .................................. 71

1.38 
Cadmium-centered radicals ................................ 74

1.39 
Indium-centered radicals................................. 74

1.40 
Tin-centered radicals................................... 75

1.41 
Tellurium-centered radicals ................................ 75

1.42 
Iodine-centered radicals ................................. 75

1.43 
Lanthanum-centered radicals............................... 76

1.44 
Tantalum-centered radicals................................ 76

1.45 
Osmium-centered radicals ................................ 77

1.46 
Iridium-centered radicals................................. 77

1.47 
Platinum-centered radicals................................ 77

1.48 
Gold-centered radicals .................................. 77

1.49 
Mercury-centered radicals................................. 78

1.50 
References for 1 ...................................... 80

2 
Organometallic (0) complexes and clusters [J.A. Howard]................ 88

2.1 
Introduction ........................................ 88

2.2 
Lithium-centered radicals ................................. 88

2.3 
Boron-centered radicals .................................. 93

2.4 
Sodium-centered radicals ................................. 95

2.5 
Aluminum-centered radicals ............................... 99

2.6 
Silicon-centered radicals .................................114

2.7 
Phosphorus-centered radicals ...............................114

2.8 
Potassium-centered radicals ...............................115

2.9 
Scandium-centered radicals ................................116

2.10 
Titanium-centered radicals................................119

2.11 
Vanadium-centered radicals ...............................119

2.12 
Chromium-centered radicals ...............................124

2.13 
Manganese-centered radicals...............................125

2.14 
Cobalt-centered radicals .................................128

2.15 
Copper-centered radicals.................................129

2.16 
Zinc-centered radicals ..................................138

2.17 
Gallium-centered radicals ................................139

2.18 
Rubidium-centered radicals ...............................142

2.19 
Yttrium-centered radicals .................................142

2.20 
Zirconium-centered radicals................................144

2.21 
Niobium-centered radicals ................................144

2.22 
Molybdenum-centered radicals ..............................146

2.23 
Rhodium-centered radicals ................................147

2.24 
Silver-centered radicals ..................................148

2.25 
Cadmium-centered radicals ................................162

2.26 
Cesium-centered radicals.................................163

2.27 
Lanthanum-centered radicals...............................163

2.28 
Tantalum-centered radicals................................164

2.29 
Tungsten-centered radicals ................................164

2.30 
Osmium-centered radicals ................................164

2.31 
Iridium-centered radicals.................................164

2.32 
Gold-centered radicals ..................................165

2.33 
Mercury-centered radicals.................................172

2.34 
References for 2 ......................................174

4 
Nonconjugated carbon radicals [A.L.J. Beckwith] .................... 179

4.1 
Introduction ........................................179

4.1.1 
General remarks ......................................179

4.1.1.1 
Nonconjugated carbon radicals ..............................179

4.1.1.2 
Notation ..........................................179

4.1.1.3 
Surveyed literature ....................................179

4.1.1.4 
Arrangement of the tables .................................179

4.1.2 
General references.....................................180

4.1.2.1 
Periodical reports.....................................180

4.1.2.2 
Books and reviews ....................................180


Primary alkyl radicals, type -CH2............................ 182

Primary alkyl radicals, type R-CH2-CH2......................... 182

Leading atom of R: Carbon ................................ 182

Leading atom of R: Other than carbon .......................... 188

Primary alkyl radicals, type R2CH-CH2 ......................... 190

Leading atom of R: Carbon ................................ 190

Leading atom of one or more of R: Other than carbon .................. 193

Primary alkyl radicals, type R3C-CH2 .......................... 196

Leading atom of R: Carbon ................................ 196

Leading atom of one or more of R: Other than carbon .................. 197

Primary alkyl radicals, type R-CH2 ...........................198

Leading atom of R: Carbon ................................ 198

R 
is acylic ......................................... 198

R 
contains a ring .....................................201

Leading atom of R: Other than carbon .......................... 215

 
Secondary alkyl radicals, type -CH- ........................... 223

Secondary alkyl radicals, type R1-CH2-CH-CH2-CH2R2 
................. 223

Secondary alkyl radicals, type R1-CH-CH2-CH2-R2 
................... 225

Leading atom of R1: Carbon ...............................225

Leading atom of R2: Carbon ...............................225

Leading atom of R2: Other than carbon .........................227

Leading atom of R1: Other than carbon .........................229

 
Secondary alkyl radicals, type R1-CH2-CH-CH2-R2 ................... 232

Leading atom of R1: Other than carbon .........................232

Leading atom of R2: Carbon ...............................232

Leading atom of R2: Other than carbon .........................233

 
Secondary alkyl radicals, type R1-CH2-CH-CHR2 .................... 233

Leading atom of R1: Carbon ...............................233

Leading atom of R1: Other than carbon .........................234

 
Secondary alkyl radicals, type R1-CH-CH2-R2...................... 237

Leading atom of R1: Carbon ...............................237

Leading atom of R2: Carbon ...............................237

Leading atom of R2: Other than carbon .........................247

Leading atom of R1: Other than carbon .........................251

Leading atom of R2: Carbon ...............................251

Leading atom of R2: Other than carbon .........................252

 
Secondary alkyl radicals, type R1-CH-CHR2 ...................... 255
2 
Leading atom of R1: Carbon ...............................255

Leading atom of R2: Carbon ...............................255

Leading atoms of R2: Carbon and other than carbon ................... 260

Leading atom of R1: Other than carbon .........................264


4.3.7 Secondary alkyl radicals, type R1-CH-CR2 ....................... 266
3

4.3.7.1 
Leading atom of R1: Carbon ...............................266

4.3.7.1.1 
Leading atom of R2: Carbon ...............................266

4.3.7.1.2 
Leading atoms of R2: Carbon and other than carbon ................... 267

4.3.7.2 	
Leading atom of R1: Other than carbon .........................268



4.3.8 
Secondary alkyl radicals, type R1-CH-R2......................... 272

4.3.8.1 
Leading atom of R1: Carbon ...............................272

4.3.8.1.1 
Leading atom of R2: Carbon ...............................272

4.3.8.1.2 
Leading atom of R2: Other than carbon .........................274

4.3.8.2 
Leading atom of R1: Other than carbon .........................275

4.3.8.2.1 
Leading atom of R2: Carbon ...............................275

4.3.8.2.1.1 
R2: Acyclic ........................................275

4.3.8.2.1.2 

R2: Cyclic......................................... 284

4.3.8.2.2 

Leading atom of R2: Other than carbon .........................287

4.4 

Tertiary alkyl radicals, type R1CR2R3........................... 290

4.4.1 

R1, R2 and R3: Leading atom is carbon .......................... 290

4.4.1.1 

R1, R2 and R3: Alkyl or substituted alkyl ......................... 290

4.4.1.2 

R1 and R2: Alkyl or substituted alkyl; R3: A functional group .............. 300

4.4.1.3 

R1 and R2: Functional groups; R3: A functional group or alkyl ............. 313

4.4.2 

R1, R2 and R3: Leading atom other than carbon ..................... 315

4.4.3 

R1 and R2: Alkyl or substituted alkyl; R3: Leading atom other than carbon ....... 325

4.4.4 

R1 and R2: Leading atom other than carbon; R3: Leading atom carbon ......... 334

4.4.5 
R1: Alkyl or substituted alkyl; R2: Carbon centered functional group; 

R3: Leading atom other than carbon ...........................338

4.5

Cyclic radicals ....................................... 342

4.5.1 

Monocyclic alkyl radicals ................................. 342

4.5.1.1

Alkyl radicals from 3-membered rings.......................... 342

4.5.1.2

Alkyl radicals from 4-membered rings.......................... 344

4.5.1.3

Alkyl radicals from 5-membered rings.......................... 346

4.5.1.3.1

 Carbocyclic radicals ...................................346


4.5.1.3.1.1 
Secondary radicals ....................................346

4.5.1.3.1.2
 Tertiary radicals ......................................348

4.5.1.3.2
 Heterocyclic radicals...................................350

4.5.1.3.2.1 
Secondary radicals ....................................350

4.5.1.3.2.2
 Tertiary radicals ......................................359

4.5.1.4 
Alkyl radicals from 6-membered rings..........................370

4.5.1.4.1
 Carbocyclic radicals ...................................370

4.5.1.4.1.1 
Secondary radicals ....................................370

4.5.1.4.1.2
 Tertiary radicals ......................................373

4.5.1.4.2 
Oxygen heterocyclic radicals...............................375

4.5.1.4.2.1 
Secondary radicals ....................................375

4.5.1.4.2.2
 Tertiary radicals ......................................385

4.5.1.4.3 
Nitrogen heterocyclic radicals ..............................393

4.5.1.4.3.1 
Secondary radicals ....................................393

4.5.1.4.3.2
 Tertiary radicals ......................................397

4.5.1.4.4 
Other heterocyclic radicals (including O,N heterocycles) ................ 399

4.5.1.5 
Alkyl radicals from 7- and higher membered rings ................... 402

4.5.2 
Polycyclicalkylradicals .................................403

4.5.2.1 
Radicals from fused rings and spiro compounds.....................403

4.5.2.1.1 
Secondary radicals ....................................403

4.5.2.1.2
 Tertiaryradicals......................................404

4.5.2.2 
Radicalsfrombridgedrings ...............................405

4.6 
s-Radicals.........................................415

4.6.1 
Acylandrelatedradicals.................................415

4.6.2 
Arylradicals .......................................417

4.6.3 
Vinylradicals.......................................418

4.7 
Referencesfor4......................................426

III General symbols and abbreviations 
A Symbols..........................................432

B Abbreviations.......................................432

C 
Substancesorpartofsubstances.............................433




VIII Table of contents 
Table of contents IX 
X 
4.2 
4.2.1 
4.2.1.1 
4.2.1.2 
4.2.2 
4.2.2.1 
4.2.2.2 
4.2.3 
4.2.3.1 
4.2.3.2 
4.2.4 
4.2.4.1 
4.2.4.1.1 
4.2.4.1.2 
4.2.4.2 
4.3 
4.3.1 
4.3.2 
4.3.2.1 
4.3.2.1.1 
4.3.2.1.2 
4.3.2.2 
4.3.3 
4.3.3.1 
4.3.3.1.1 
4.3.3.1.2 
4.3.4 
4.3.4.1 
4.3.4.2 
4.3.5 
4.3.5.1 
4.3.5.1.1 
4.3.5.1.2 
4.3.5.2 
4.3.5.2.1 
4.3.5.2.2 
4.3.6 
4.3.6.1 
4.3.6.1.1 
4.3.6.1.2 
4.3.6.2 
Table of contents 
Table of contents 	XI 
 
 XII Table of contents 
