Table of contents 
Magnetic properties of non-metallic inorganic compounds based on transition elements 
Subvolume I 5: Phyllosilicates  Part 2 
List of frequently used symbols and abbreviations........................ X 
 Symbols............................................. X 
 Abbreviations..... ....................................XIII 

8 	Magnetic and related properties of silicates and phosphates 
8.1 	Silicates (E. BURZO) 
8.1.1	 Orthosilicates ............................... see subvolume III/27I1 

8.1.2 	Sorosilicates................................ see subvolume III/27I2 

8.1.3 	Cyclosilicates ............................... see subvolume III/27I3 

8.1.4 	Inosilicates ................................ see subvolume III/27I4 

8.1.5 	Phyllosilicates ........................................... 

8.1.5.1 	Gillespite group of silicates ....................... see subvolume III/27I5a 

8.1.5.2 	Apophyllite-type silicates ........................ see subvolume III/27I5a 

8.1.5.3 	Natrosilites and related silicates ..................... see subvolume III/27I5a 

8.1.5.4 	Pyrophyllite, talc and related silicates .................. see subvolume III/27I5a 

8.1.5.5	 True micas ............................... see subvolume III/27I5a 

8.1.5.6 	Brittle micas and related silicates .................... see subvolume III/27I5a 

8.1.5.7 	Interlayer deficient micas, stilpnomelane, ganophyllite group ...... see subvolume III/27I5a 
8.1.5.8 	Smectites and related silicates ...................... see subvolume III/27I5a 

8.1.5.9 	Chlorites and related silicates .................................. 1 

8.1.5.9.1 	Crystal structure. Lattice parameters .............................. 1 

8.1.5.9.1.1	 Chlorite polytype symbols.................................... 1 

8.1.5.9.1.2	 Crystal structures ........................................ 4 

8.1.5.9.2 	Neutron diffraction data .................................... 16 

8.1.5.9.3  	Magnetic properties ...................................... 16 

8.1.5.9.4 	Nuclear gamma resonance (NGR) data ............................ 17 

8.1.5.9.5 	Nuclear magnetic resonance (NMR) data ........................... 19 

8.1.5.9.6 	Electron paramagnetic resonance (EPR) data ......................... 20 

8.1.5.9.7 	Specific heat data ....................................... 20 

8.1.5.9.8	 EXAFS spectra ........................................ 20 

8.1.5.9.9	 Optical properties ....................................... 21 
Tables and Figures ...................................... 23 
References for 8.1.5.9 ..................................... 76 

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 Table of contents 
8.1.5.10 	Kaolin group and related silicates ............................... 81 

8.1.5.10.1 	Crystal structure. Lattice parameters ............................. 81 

8.1.5.10.2	 Magnetic properties ...................................... 97 

8.1.5.10.3 	Nuclear gamma resonance (NGR) data ............................ 98 

8.1.5.10.4 	Nuclear magnetic resonance (NMR) data ........................... 100 

8.1.5.10.5 	Electron paramagnetic resonance (EPR) data ......................... 106 

8.1.5.10.6	 Dielectric properties...................................... 110 

8.1.5.10.7	 Heat capacity ......................................... 111 

8.1.5.10.8 	Infrared and Raman studies .................................. 111 

8.1.5.10.9	 Optical absorption spectra ................................... 117 
Tables and Figures ...................................... 119 
References for 8.1.5.10 .................................... 186 

8.1.5.11 	Serpentines and related silicates ................................ 199 

8.1.5.11.1 	Crystal structure and lattice parameters ............................ 199 

8.1.5.11.2	 Magnetic properties ...................................... 224 

8.1.5.11.3 	Neutron diffraction data .................................... 224 

8.1.5.11.4 	Nuclear gamma resonance (NGR) data ............................ 225 

8.1.5.11.5 	Nuclear magnetic resonance (NMR) data ........................... 227 

8.1.5.11.6 	Electron paramagnetic resonance (EPR) data ......................... 228 

8.1.5.11.7	 Electrical resistivity ...................................... 228 

8.1.5.11.8	 Thermal properties ...................................... 228 

8.1.5.11.9	 Infrared spectra ........................................ 229 
Tables and Figures ...................................... 233 
References for 8.1.5.11 .................................... 293 

8.1.5.12 	Halloysite and pyrosmalite groups of silicates ......................... 301 

8.1.5.12.1 	Crystal structure. Lattice parameters ............................. 301 

8.1.5.12.2 	Nuclear gamma resonance (NGR) data and magnetic properties................ 310 

8.1.5.12.3 	Nuclear magnetic resonance (NMR) data ........................... 311 

8.1.5.12.4 	Electron paramagnetic resonance (EPR) data ......................... 312 

8.1.5.12.5	 Optical properties ....................................... 312 
Tables and Figures ...................................... 315 
References for 8.1.5.12 .................................... 335 

8.1.5.13 	Sepiolite and palygorskite group of silicates.......................... 340 

8.1.5.13.1 	Crystal structures. Lattice parameters ............................. 340 

8.1.5.13.2 	Nuclear gamma resonance (NGR) data ............................ 353 

8.1.5.13.3 	Nuclear magnetic resonance (NMR) data ........................... 353 

8.1.5.13.4 	Electron paramagnetic resonance (EPR) data ......................... 356 

8.1.5.13.5 	Electrical properties and dielectric behavior .......................... 356 

8.1.5.13.6	 Optical properties ....................................... 357 
Tables and Figures ...................................... 362 
References for 8.1.5.13 .................................... 398 

8.1.5.14 	Reyerite, rhodesite groups of silicates and related phases ................... 404 

8.1.5.14.1 	Crystal structures. Lattice parameters. ............................. 404 

8.1.5.14.2 	Nuclear magnetic resonance (NMR) data ........................... 414 

8.1.5.14.3	 Optical data .......................................... 415 
Tables and figures ....................................... 416 
References for 8.1.5.14 .................................... 439 

8.1.5.15 	Kanemite and ekanite groups and related silicates ....................... 442 

8.1.5.15.1 	Crystal structures. Lattice parameters ............................. 442 

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 Table of contents 
8.1.5.15.2 	Nuclear magnetic resonance (NMR) data ........................... 450 

8.1.5.15.3 	IR and Raman data ...................................... 453 
Tables and Figures ...................................... 456 
References for 8.1.5.15 .................................... 484 

8.1.5.16 	Tuscanite, vertumnite, aminoffite, surite, cymrite and related silicates............. 488 

8.1.5.16.1 	Crystal structures. Lattice parameters ............................. 488 

8.1.5.16.2 	Nuclear magnetic resonance (NMR) data ........................... 495 

8.1.5.16.3	 Specific heat ......................................... 495 

8.1.5.16.4 	IR, Raman and optical data .................................. 495 
Tables and Figures ...................................... 498 
References for 8.1.5.16 .................................... 522 

8.1.5.17 	Cavansite, eakerite, magadiite, kenyaite, bikitaite, petalite, prehnite and related silicates ... 524 
8.1.5.17.1 	Crystal structures. Lattice parameters ............................. 524 

8.1.5.17.2	 Magnetic properties ...................................... 533 

8.1.5.17.3 	Nuclear gamma resonance (NGR) data ............................ 533 

8.1.5.17.4 	Nuclear magnetic resonance (NMR) data ........................... 534 

8.1.5.17.5 	Electron paramagnetic resonance (EPR) data ......................... 535 

8.1.5.17.6	 Specific heat ......................................... 536 

8.1.5.17.7	 Optical data .......................................... 536 
Tables and Figures ...................................... 540 
References for 8.1.5.17 .................................... 571 

Index of substances for Volume III/27I5 ........................... 575 
 A) Alphabetical index of element systems........................... 576 
B) Alphabetical index of mineral names............................ 589 

Landolt-Brnstein New Series III/27 I5 




