Contents 


1 Introduction ...................................... 1-1 

1.1 General features of state behavior of binary liquid mixtures............... 1-1 

1.1.1 Basic relations...................................... 1-1 

1.1.2 Derived volumetric quantities .............................. 1-2 

1.1.3 Volumetric properties of ideal mixture ......................... 1-3 

1.1.4 	Dependence of volumetric quantities on composition .................. 1-4 

1.2 	Experimental and derived quantities .......................... 1-6 

1.3 	Characterization of main groups of experimental methods used for measurements of  volumetric properties of liquid mixtures......................... 1-7 
1.3.1 	Pycnometers and dilatometers .............................. 1-8 

1.3.2 	Mixing dilatometers ................................... 1-8 

1.3.3 	Piezometers ....................................... 1-9 

1.3.4 	Vibrating-tube densimeters ............................... 1-9 

1.3.5 	Buoyancy methods ................................... 1-10 

1.3.6 	Speed-of-sound method ................................. 1-10 

1.3.7 	Piezothermal method .................................. 1-11 

1.4 	Analysis of experimental uncertainties ......................... 1-11 

1.4.1 	Estimation of uncertainty of mixture density calculated from excess volume ...... 1-11 
1.4.2 	Estimation of uncertainty of excess volume calculated from mixture density ...... 1-12 
1.4.3 	Estimation of uncertainty of isentropic compressibility calculated from density and speed of sound ..................................... 1-13 
1.5 	Correlations ....................................... 1-13 

1.5.1 	Correlation of mixture density as a function of composition (constant T, P)....... 1-14 

1.5.2 	Correlation of excess volume as a function of composition (constant T, P) ....... 1-14 

1.5.3 	Correlation of dependence on temperature (constant P, x1) ............... 1-15 

1.5.4 	Correlation of dependence on pressure (constant T, x1) ................. 1-15 

2 	Tables on volumetric properties............................ 2-1 

2.1 	Introduction ....................................... 2-1 

2.1.1 	Property types ...................................... 2-2 

2.2 	Organic systems..................................... 2-7 

2.3 	Aqueous-organic systems ............................... 2-389 

2.4 	Systems containing inorganic substances ....................... 2-428 

3 	Instructions on using the computer program ELBT ................. 3-1 

3.1 	Introduction ....................................... 3-1 

3.2 	System requirements .................................. 3-1 

3.3 	Installing the program .................................. 3-1 

 Contents IX 
3.4 To start ......................................... 3-2 

3.5 Visualization of numerical data ............................. 3-3 

3.5.1 PDF display ....................................... 3-3 

3.5.2 SELF (Standard Electronic File) display ........................ 3-3 

3.5.2.1 SELF structure. Identifiers ............................... 3-4 

3.5.2.2 Physical quantities and physico-chemical properties .................. 3-5 

3.5.2.3 Independent variables and dependent variables ..................... 3-6 

3.5.2.4 Parameters ....................................... 3-6 

3.5.2.5 Symbols, units and scales of physical quantities..................... 3-6 

3.5.2.6 Numerical data and estimated uncertainties ....................... 3-6 

3.5.2.7 Two-phase liquid-liquid systems ............................ 3-7 

3.5.2.8 Linked data files..................................... 3-7 

3.5.3 ELDATA display .................................... 3-8 

3.5.3.1 Selection of units .................................... 3-9 

3.5.4 Graphical display .................................... 3-9 

3.5.5 Correlating experimental data .............................. 3-10 

3.5.6 Output of correlated experimental data ......................... 3-11 

3.6 Creating SpreadsheetML documents .......................... 3-14 

4 Indexes ......................................... 4-1 

4.1 Formula index of substances .............................. 4-2 

4.2 Name index of substances ................................ 4-7 

4.3 Class index of organic substances ............................ 4-24 

4.4 Class index of organic systems ............................. 4-27 

4.5 Class index of aqueous-organic systems......................... 4-94 

4.6 Index of systems containing inorganic substances .................... 4-97 

5 General References .................................. 5-1 


