 Contents
Introduction
Linear Combination of AtomicOrbitals
H2 and He2 -The
Simplest Examples
Demonstration 1
The
Effect of Electronegativity
Demonstration 2
p-Orbitals
and p-Overlap
Demonstration 3
Combining
AOs to Build MOs
Methylene, CH2
Demonstration 4
The
AH2 Walsh Diagram
Demonstration 5
Larger Molecules
Ethylene
Cyclopropane
p-Systems
Linear Systems
Cyclic Systems
Hyperconjugation
The Ethyl Cation
The Cyclopropylcarbinyl Cation
Negative Hyperconjugation
The Anomeric Effect
Reactions
Lewis Acid/Lewis Base Interactions
SN2 Reactions
Selectivity;
Frontier MO Theory
Nucleophilic Oxirane
Ring-Opening
The
Woodward-Hoffmann Rules
Electrocyclic Reactions
Cycloadditions
Sigmatropic Rearrangements
Elementary Symmetry
Symmetry Elements
The Identity
Proper Rotation Axes
Mirror Planes
Improper Rotation Axes
Inversion Centres
Point
Groups
Irreducible
Representations and Character Tables
Degenerate
Orbitals
Glossary
Molecules in VRML
General Information - Installation -Use
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